From: Subject: BROMOPHENOL BLUE Date: Wed, 10 Dec 2008 11:17:22 -0500 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_0000_01C95AB8.DF9D7390" X-MimeOLE: Produced By Microsoft MimeOLE V6.00.2900.5579 This is a multi-part message in MIME format. ------=_NextPart_000_0000_01C95AB8.DF9D7390 Content-Type: text/html; charset="Windows-1252" Content-Transfer-Encoding: quoted-printable Content-Location: http://www.jtbaker.com/msds/englishhtml/b5056.htm BROMOPHENOL BLUE

MSDS Number: B5056 * * * * * Effective Date: 03/14/07 * = * * * *=20 Supercedes: 08/10/04

BROMOPHENOL BLUE

1. Product Identification

Synonyms: 3,3',5,5'-Tetrabromophenol sulfonphthalein; = 4,4'-(3H-2,1-benzoxathiol-3-ylidene)bis[2,6-dibromophenol]S ,S dioxide =
CAS No.: 115-39-9
Molecular Weight: 670.02=20
Chemical Formula: C19H10Br4O5S
Product Codes: = D293=20

2. Composition/Information on Ingredients

  Ingredient  =
                              CAS No         Percent        Hazardous    =
                             =20
  ---------------------------------------   ------------   ------------  =
 ---------  =20
=20
  Bromophenol Blue                          115-39-9         90 - 100%   =
    Yes                                                                  =
 =20
=20

3. Hazards Identification

Emergency Overview
--------------------------=20
CAUTION! MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE = IRRITATION=20 TO SKIN, EYES, AND RESPIRATORY TRACT.=20

SAF-T-DATA^(tm) Ratings (Provided here for = your=20 convenience)=20 =
---------------------------------------------------------------------= --------------------------------------=20
Health Rating: 1 - Slight
Flammability Rating: 1 - Slight=20
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate =
Lab=20 Protective Equip: GOGGLES; LAB COAT; PROPER GLOVES
Storage Color = Code:=20 Green (General Storage)=20 =
---------------------------------------------------------------------= --------------------------------------=20

Potential Health Effects =
----------------------------------=20

Inhalation:
May cause irritation to the respiratory = tract.=20 Symptoms may include coughing and shortness of breath. =
Ingestion:=20
Effects not determined. Large oral doses may cause irritation to = the=20 gastrointestinal tract.
Skin Contact:
May cause = irritation with=20 redness and pain.
Eye Contact:
May cause irritation, = redness=20 and pain.
Chronic Exposure:
Not determined. =
Aggravation=20 of Pre-existing Conditions:
No information found. =

4. First Aid Measures

Inhalation:
Remove to fresh air. Get medical = attention=20 for any breathing difficulty.
Ingestion:
Induce = vomiting=20 immediately as directed by medical personnel. Never give anything by = mouth to=20 an unconscious person. Get medical attention.
Skin Contact: =
Immediately flush skin with plenty of water for at least 15 = minutes.=20 Remove contaminated clothing and shoes. Wash clothing before reuse. = Thoroughly=20 clean shoes before reuse. Get medical attention if irritation = develops.=20
Eye Contact:
Immediately flush eyes with plenty of = water for at=20 least 15 minutes, lifting upper and lower eyelids occasionally. Get = medical=20 attention if irritation persists.

5. Fire Fighting Measures

Fire:
As with most organic solids, fire is = possible at=20 elevated temperatures or by contact with an ignition source.=20
Explosion:
Fine dust dispersed in air in sufficient=20 concentrations, and in the presence of an ignition source is a = potential dust=20 explosion hazard.
Fire Extinguishing Media:
Water = spray, dry=20 chemical, alcohol foam, or carbon dioxide.
Special = Information:=20
In the event of a fire, wear full protective clothing and = NIOSH-approved=20 self-contained breathing apparatus with full facepiece operated in the = pressure demand or other positive pressure mode.

6. Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or = spill.=20 Wear appropriate personal protective equipment as specified in Section = 8.=20 Spills: Clean up spills in a manner that does not disperse dust into = the air.=20 Use non-sparking tools and equipment. Reduce airborne dust and prevent = scattering by moistening with water. Pick up spill for recovery or = disposal=20 and place in a closed container.

7. Handling and Storage

Keep in a tightly closed container. Protect from physical = damage.=20 Store in a cool, dry, ventilated area away from sources of heat, = moisture and=20 incompatibilities. Containers of this material may be hazardous when = empty=20 since they retain product residues (dust, solids); observe all = warnings and=20 precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.=20
Ventilation System:
A system of local and/or general = exhaust is=20 recommended to keep employee exposures as low as possible. Local = exhaust=20 ventilation is generally preferred because it can control the = emissions of the=20 contaminant at its source, preventing dispersion of it into the = general work=20 area. Please refer to the ACGIH document, Industrial Ventilation, A = Manual=20 of Recommended Practices, most recent edition, for details.=20
Personal Respirators (NIOSH Approved):
For conditions = of use=20 where exposure to dust or mist is apparent and engineering controls = are not=20 feasible, a particulate respirator (NIOSH type N95 or better filters) = may be=20 worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, = etc.) are=20 present, use a NIOSH type R or P filter. For emergencies or instances = where=20 the exposure levels are not known, use a full-face positive-pressure,=20 air-supplied respirator. WARNING: Air-purifying respirators do not = protect=20 workers in oxygen-deficient atmospheres.
Skin Protection: =
Wear=20 protective gloves and clean body-covering clothing.
Eye = Protection:=20
Use chemical safety goggles. Maintain eye wash fountain and = quick-drench=20 facilities in work area.

9. Physical and Chemical Properties

Appearance:
Tan to orange, light pink to purple = or red=20 crystalline powder.
Odor:
Slightly amine to odorless.=20
Solubility:
0.4g/100g water @ 20C (68F). =
Specific=20 Gravity:
No information found.
pH:
No = information=20 found.
% Volatiles by volume @ 21C (70F):
0 =
Boiling=20 Point:
279C (534F)
Melting Point:
273C (523F)=20
Vapor Density (Air=3D1):
No information found. =
Vapor=20 Pressure (mm Hg):
No information found.
Evaporation = Rate=20 (BuAc=3D1):
No information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of = use and=20 storage.
Hazardous Decomposition Products:
Burning may = produce=20 bromines, sulfur oxides, carbon dioxide, and carbon monoxide. =
Hazardous=20 Polymerization:
Will not occur.
Incompatibilities:=20
Strong oxidizers.
Conditions to Avoid:
Heat, = flames,=20 ignition sources and incompatibles.

11. Toxicological Information

No LD50/LC50 information found relating to normal routes = of=20 occupational exposure. Investigated as a mutagen. =

  --------\Cancer =
Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC =
Category
  ------------------------------------   -----    -----------    =
-------------
  Bromophenol Blue (115-39-9)             No          No            None

12. Ecological Information

Environmental Fate:
No information found.=20
Environmental Toxicity:
No information found. =

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be = managed in an appropriate and approved waste disposal facility. = Processing,=20 use or contamination of this product may change the waste management = options.=20 State and local disposal regulations may differ from federal disposal=20 regulations. Dispose of container and unused contents in accordance = with=20 federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

  --------\Chemical Inventory Status - =
Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  =
Australia
  -----------------------------------------------  ----  ---  -----  =
---------
  Bromophenol Blue (115-39-9)                       Yes  Yes   Yes      =
Yes                                     =20
=20
  --------\Chemical Inventory Status - Part =
2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  =
Phil.
  -----------------------------------------------  -----  ---   ----  =
-----
  Bromophenol Blue (115-39-9)                       Yes   Yes   No     =
Yes       =20
=20
  --------\Federal, State & International Regulations - Part =
1\----------------
                                             -SARA 302-    ------SARA =
313------
  Ingredient                                 RQ    TPQ     List  =
Chemical Catg.
  -----------------------------------------  ---   -----   ----  =
--------------
  Bromophenol Blue (115-39-9)                No    No      No         No
=20
  --------\Federal, State & International Regulations - Part =
2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d)=20
  -----------------------------------------  ------     ------    ------
  Bromophenol Blue (115-39-9)                No         No         No    =
 =20
=20
=20
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)=20

Australian Hazchem Code: None allocated.=20
Poison Schedule: None allocated.
WHMIS:
This = MSDS=20 has been prepared according to the hazard criteria of the Controlled = Products=20 Regulations (CPR) and the MSDS contains all of the information = required by the=20 CPR.

16. Other Information

NFPA Ratings: Health: 1 Flammability: 1 = Reactivity: 0
Label Hazard Warning:
CAUTION! MAY = BE=20 HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE IRRITATION TO SKIN, EYES, = AND=20 RESPIRATORY TRACT.
Label Precautions:
Avoid contact = with eyes,=20 skin and clothing.
Avoid breathing dust.
Keep container = closed.
Use=20 with adequate ventilation.
Wash thoroughly after=20 handling.

Label First Aid:
If inhaled, remove to = fresh=20 air. Get medical attention for any breathing difficulty. If swallowed, = induce=20 vomiting immediately as directed by medical personnel. Never give = anything by=20 mouth to an unconscious person. In case of contact, immediately flush = eyes or=20 skin with plenty of water for at least 15 minutes. Get medical = attention if=20 irritation develops or persists.
Product Use: =
Laboratory=20 Reagent.
Revision Information:
MSDS Section(s) changed = since=20 last revision of document include: 3.
Disclaimer:=20 =
*********************************************************************= ***************************=20
Mallinckrodt Baker, Inc. provides the information contained = herein in=20 good faith but makes no representation as to its comprehensiveness or=20 accuracy. This document is intended only as a guide to the appropriate = precautionary handling of the material by a properly trained person = using this=20 product. Individuals receiving the information must exercise their = independent=20 judgment in determining its appropriateness for a particular purpose.=20 MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, = EITHER=20 EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF=20 MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE=20 INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION = REFERS.=20 ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR = DAMAGES=20 RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.=20 =
*********************************************************************= ***************************=20
Prepared by: Environmental Health & Safety
Phone = Number:=20 (314) 654-1600 (U.S.A.)

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